Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
---|---|---|---|---|---|---|
(R)-S-(2-pyridyl)cysteine N-oxide | Allium stipitatum | - |
2-sulfanylpyridine N-oxide + 2-aminoacrylate | 2-sulfanylpyridine N-oxide can spontaneously rearrange into tautomeric and more stable N-hydroxypyridine-(1H)-thione, which can be transformed to 2-(methyldithio)pyridine N-oxide, 2-[(methylthio)methyldithio]pyridine N-oxide, di(2-pyridyl) disulfide N-oxide, and di(2-pyridyl) disulfide N,N'-dioxide | ? | |
methiin | Allium stipitatum | - |
methanesulfenic acid + 2-aminoacrylate | - |
? | |
S-(methylthiomethyl)cysteine 4-oxide | Allium stipitatum | i.e. marasmin | (methylthio)methane-sulfenic acid + 2-aminoacrylate | - |
? |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Allium stipitatum | - |
- |
- |
Source Tissue | Comment | Organism | Textmining |
---|---|---|---|
bulb | - |
Allium stipitatum | - |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
(R)-S-(2-pyridyl)cysteine N-oxide | - |
Allium stipitatum | 2-sulfanylpyridine N-oxide + 2-aminoacrylate | 2-sulfanylpyridine N-oxide can spontaneously rearrange into tautomeric and more stable N-hydroxypyridine-(1H)-thione, which can be transformed to 2-(methyldithio)pyridine N-oxide, 2-[(methylthio)methyldithio]pyridine N-oxide, di(2-pyridyl) disulfide N-oxide, and di(2-pyridyl) disulfide N,N'-dioxide | ? | |
methiin | - |
Allium stipitatum | methanesulfenic acid + 2-aminoacrylate | - |
? | |
S-(methylthiomethyl)cysteine 4-oxide | i.e. marasmin | Allium stipitatum | (methylthio)methane-sulfenic acid + 2-aminoacrylate | - |
? |