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Literature summary for 3.3.2.8 extracted from

  • Van der Werf, M.J.; Orru, R.V.A.; Overkamp, K.M.; Swarts, H.J.; Ospiran, I.; Steinreiber, A.; de Bont, J.A.M.; Faber, K.
    Substrate specificity and stereospecificity of limonene-1,2-epoxide hydrolase from Rhodococcus erythropolis DCL14; an enzyme showing sequential and enantioconvergent substrate conversion (1999), Appl. Microbiol. Biotechnol., 52, 380-385.
No PubMed abstract available

Localization

Localization Comment Organism GeneOntology No. Textmining
cytoplasm
-
Rhodococcus erythropolis 5737
-

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
(1R,2S,4R)-limonene-1,2-epoxide + H2O Rhodococcus erythropolis
-
(1S,2S,4R)-limonene-1,2-diol optically pure, diastereomeric excess above 99% ?
(1R,2S,4S)-limonene-1,2-epoxide + H2O Rhodococcus erythropolis
-
(1R,2R,4S)-limonene-1,2-diol optically pure, diastereomeric excess above 99% ?
(1S,2R,4R)-limonene-1,2-epoxide + H2O Rhodococcus erythropolis
-
(1S,2S,4R)-limonene-1,2-diol optically pure, diastereomeric excess above 99% ?
(1S2R4S)-limonene-1,2-epoxide + H2O Rhodococcus erythropolis
-
(1R,2R,4S)-limonene-1,2-diol optically pure, diastereomeric excess above 99% ?

Organism

Organism UniProt Comment Textmining
Rhodococcus erythropolis
-
-
-

Reaction

Reaction Comment Organism Reaction ID
1,2-epoxymenth-8-ene + H2O = menth-8-ene-1,2-diol catalyzes simultaneous sequential and enantioconvergent epoxide conversion Rhodococcus erythropolis

Specific Activity [micromol/min/mg]

Specific Activity Minimum [µmol/min/mg] Specific Activity Maximum [µmol/min/mg] Comment Organism
85.1
-
with (1R,2S,4R)-limonene-1,2-epoxide as substrate Rhodococcus erythropolis

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(1R,2S,4R)-limonene-1,2-epoxide + H2O
-
Rhodococcus erythropolis (1S,2S,4R)-limonene-1,2-diol optically pure, diastereomeric excess above 99% ?
(1R,2S,4S)-limonene-1,2-epoxide + H2O
-
Rhodococcus erythropolis (1R,2R,4S)-limonene-1,2-diol optically pure, diastereomeric excess above 99% ?
(1S,2R,4R)-limonene-1,2-epoxide + H2O
-
Rhodococcus erythropolis (1S,2S,4R)-limonene-1,2-diol optically pure, diastereomeric excess above 99% ?
(1S2R4S)-limonene-1,2-epoxide + H2O
-
Rhodococcus erythropolis (1R,2R,4S)-limonene-1,2-diol optically pure, diastereomeric excess above 99% ?
1,2-epoxy-2,6-dimethyl-5-heptene + H2O
-
Rhodococcus erythropolis (2S)-2,6-dimethyl-5-hepten-1,2-diol
-
?
1,2-epoxy-2-methyl-6-heptene + H2O
-
Rhodococcus erythropolis (2S)-2-methyl-6-heptene-1,2-diol
-
?
1,2-epoxy-2-methylheptane + H2O
-
Rhodococcus erythropolis (2S)-2-methylheptane-1,2-diol
-
?
1,2-epoxy-3-benzyl-2-methylpropane + H2O
-
Rhodococcus erythropolis (2S)-3-benzyl-2-methylpropane-1,2-diol
-
?
1-methylcyclohexene oxide + H2O
-
Rhodococcus erythropolis (1S,2S)-1-methylcyclohexane-1,2-diol
-
?
cyclohexene oxide + H2O
-
Rhodococcus erythropolis (1S,2S)-trans cyclohexanediol + (1R,2R)-trans-cyclohexanediol
-
?
indene oxide + H2O
-
Rhodococcus erythropolis indane-1,2-diol
-
?