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Literature summary for 3.1.1.20 extracted from

  • Yu, X.; Li, Y.; Wu, D.
    Enzymatic synthesis of gallic acid esters using microencapsulated tannase: effect of organic solvents and enzyme specificity (2004), J. Mol. Catal. B, 30, 69-73.
No PubMed abstract available

Application

Application Comment Organism
synthesis synthesis of gallic esters from gallic acid and alcohols in organic solvents using enzyme microencapsulated with chitosan-alginate complex coacervate membrane. Highest yield is 44.3% in benzene, and 35.7% in hexane, best substrates are 1-propanol, 1-butanol, or 1-pentanol Aspergillus niger

Organism

Organism UniProt Comment Textmining
Aspergillus niger
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
gallate + 1-butanol 85% of the yield with 1-propanol Aspergillus niger 1-butyl gallate + H2O
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gallate + 1-hexanol 2% of the yield with 1-propanol Aspergillus niger 1-hexyl gallate + H2O
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gallate + 1-pentanol 77% of the yield with 1-propanol Aspergillus niger 1-pentyl gallate + H2O
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gallate + ethanol 5% of the yield with 1-propanol Aspergillus niger ethyl gallate + H2O
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gallate + methanol 2% of the yield with 1-propanol Aspergillus niger methyl gallate + H2O
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gallate + propan-1-ol
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Aspergillus niger propyl gallate + H2O
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