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Literature summary for 2.4.1.7 extracted from

  • Luley-Goedl, C.; Sawangwan, T.; Brecker, L.; Wildberger, P.; Nidetzky, B.
    Regioselective O-glucosylation by sucrose phosphorylase: a promising route for functional diversification of a range of 1,2-propanediols (2010), Carbohydr. Res., 345, 1736-1740.
    View publication on PubMed
Search for more literature for 2.4.1.7

Cloned(Commentary)

Cloned (Comment) Organism
expression in Escherihia coli strain DH10B Leuconostoc mesenteroides

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
sucrose + phosphate Leuconostoc mesenteroides
-
 D-fructose + alpha-D-glucose 1-phosphate
-
 ?

Organism

Organism UniProt Comment Textmining
Leuconostoc mesenteroides
-
-
-

Reaction

Reaction Comment Organism Reaction ID
sucrose + phosphate = D-fructose + alpha-D-glucose 1-phosphate reaction mechanism of transglucosylation, overview. Formation of 2-O- and 4-O-glycosidic isomers of alpha-D-glucopyranosyl glucose suggests that catalytic glucosyl transfer by the phosphorylase involves two different binding modes for the D-glucose acceptor Leuconostoc mesenteroides
a

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
additional information glucobioses, maltose, i.e. 4-O-alpha-D-glucopyranosyl glucose, and kojibiose, i.e. 2-O-alpha-D-glucopyranosyl glucose, are formed in large amounts by glucosyl transfer to glucose, exceeding in almost all cases the amount of the desired transfer product from 1,2-propandiol compounds, process optimization, overview. Formation of 2-O- and 4-O-glycosidic isomers of alpha-D-glucopyranosyl glucose suggests that catalytic glucosyl transfer by the phosphorylase involves two different binding modes for the D-glucose acceptor, structure-activity relationships, overview Leuconostoc mesenteroides ?
-
 ?
sucrose + 1,2-propanediol regioselective glucosylation Leuconostoc mesenteroides D-fructose + 2-O-(alpha-D-glucopyranosyl)-1,2-propanediol
-
 ?
sucrose + 3-(3-methoxyphenoxy)-1,2-propanediol regioselective glucosylation Leuconostoc mesenteroides D-fructose + 3-(3-methoxyphenoxy)-2-O-(alpha-D-glucopyranosyl)-1,2-propanediol
-
 ?
sucrose + 3-allyloxy-1,2-propanediol regioselective glucosylation Leuconostoc mesenteroides D-fructose + 3-allyloxy-2-O-(alpha-D-glucopyranosyl)-1,2-propanediol
-
 ?
sucrose + 3-ethoxy-1,2-propanediol regioselective glucosylation Leuconostoc mesenteroides D-fructose + 3-ethoxy-2-O-(alpha-D-glucopyranosyl)-1,2-propanediol product distribution resulting from conversion of sucrose in the presence of 3-ethoxy-1,2-propanediol, overview ?
sucrose + 3-methoxy-1,2-propanediol regioselective glucosylation Leuconostoc mesenteroides D-fructose + 3-methoxy-2-O-(alpha-D-glucopyranosyl)-1,2-propanediol
-
 ?
sucrose + 3-tert-butoxy-1,2-propanediol regioselective glucosylation Leuconostoc mesenteroides D-fructose + 3-tert-butoxy-2-O-(alpha-D-glucopyranosyl)-1,2-propanediol
-
 ?
sucrose + phosphate
-
 Leuconostoc mesenteroides D-fructose + alpha-D-glucose 1-phosphate
-
 ?
sucrose + phosphate regioselective glucosylation Leuconostoc mesenteroides D-fructose + alpha-D-glucose 1-phosphate
-
 ?

Temperature Optimum [°C]

Temperature Optimum [°C] Temperature Optimum Maximum [°C] Comment Organism
30
-
 assay at Leuconostoc mesenteroides

pH Optimum

pH Optimum Minimum pH Optimum Maximum Comment Organism
7
-
 assay at Leuconostoc mesenteroides