1.1.1.260: sulcatone reductase

This is an abbreviated version!
For detailed information about sulcatone reductase, go to the full flat file.

Reaction

ECTree

     1 Oxidoreductases

         1.1 Acting on the CH-OH group of donors

             1.1.1 With NAD⁺ or NADP⁺ as acceptor

                1.1.1.260 sulcatone reductase

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Results	in table
7	Application
1	CAS Registry Number
13	Cofactor
21	Natural Substrates/ Products (Substrates)
11	Organism
1	Purification (Commentary)
1	Reaction
3	Reaction Type
11	Reference
11	Source Tissue
21	Substrates and Products (Substrate)
1	Systematic Name

Natural Substrates Products

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Natural Substrates Products on EC 1.1.1.260 - sulcatone reductase

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NATURAL SUBSTRATE

NATURAL PRODUCT

REACTION DIAGRAM

ORGANISM

UNIPROT

COMMENTARY
(Substrate)

LITERATURE
(Substrate)

COMMENTARY
(Product)

LITERATURE
(Product)

REVERSIBILITY
r=reversible
ir=irreversible
?=not specified

6-methylhept-5-en-2-one + NADH

6-methylhept-5-en-2-ol + NAD+

13 entries

6-methylhept-5-en-2-one + NADH

6-methylhept-5-en-2-ol + NAD+

Aspergillus niger

-

sulcatone

207955

sulcatol, 80% sulcatol R(-) enantiomer after 24 h reaction time

207955

r

6-methylhept-5-en-2-one + NADH

6-methylhept-5-en-2-ol + NAD+

Clostridium tyrobutyricum

-

enantiomeric selectivity substantially affected by pregrowth period and substrate concentration

207953

sulcatol

207953

r

6-methylhept-5-en-2-one + NADH

6-methylhept-5-en-2-ol + NAD+

Clostridium tyrobutyricum

-

sulcatone

207953

sulcatol

207953

r

6-methylhept-5-en-2-one + NADH

6-methylhept-5-en-2-ol + NAD+

Clostridium tyrobutyricum

-

sulcatone

207954

sulcatol

207954

r

6-methylhept-5-en-2-one + NADH

6-methylhept-5-en-2-ol + NAD+

Clostridium tyrobutyricum

-

sulcatone

207955

sulcatol, 80% of sulcatol R enantiomer after 48 h reaction time

207955

r

6-methylhept-5-en-2-one + NADH

6-methylhept-5-en-2-ol + NAD+

Clostridium tyrobutyricum PON5

-

sulcatone

207954

sulcatol

207954

r

6-methylhept-5-en-2-one + NADH

6-methylhept-5-en-2-ol + NAD+

Geotrichum candidum

-

sulcatone

207955

96% sulcatol R enantiomer after 17 h reaction time, sulcatol

207955

r

6-methylhept-5-en-2-one + NADH

6-methylhept-5-en-2-ol + NAD+

Gnathotrichus retusus

-

sulcatone

207955

only sensitive to S enantiomer, inhibited by the R enantiomer, sulcatol

207955

r

6-methylhept-5-en-2-one + NADH

6-methylhept-5-en-2-ol + NAD+

Gnathotrichus sulcatus

-

sulcatone

207955

sulcatol, mixture of 65% S(+)- and 35% S(-)-sulcatol isomers

207955

r

6-methylhept-5-en-2-one + NADH

6-methylhept-5-en-2-ol + NAD+

Levilactobacillus brevis

-

sulcatone

207953

sulcatol

207953

r

6-methylhept-5-en-2-one + NADH

6-methylhept-5-en-2-ol + NAD+

Levilactobacillus brevis

-

R(-)-sulcatol in high enantiomeric excess formed irrespective of pregrowth period and substrate concentration

207953

sulcatol

207953

r

6-methylhept-5-en-2-one + NADH

6-methylhept-5-en-2-ol + NAD+

Saccharomyces cerevisiae

-

sulcatone

207955

sulcatol, S enantiomer formed

207955

r

6-methylhept-5-en-2-one + NADH

6-methylhept-5-en-2-ol + NAD+

Thermoanaerobacter brockii

-

sulcatone

207955

100% enantiomeric excess for S(+)-sulcatol, sulcatol, S enantiomer formed

207955

r